For redundancy, which it sounds like you are into, keep the 100 watt panels on a separate charge controller. If one of the two controllers kick the bucket you still have a functional one to limp by till you replace the DOA controller.
You can series wire two 100 watt panels to get similar voltage to the 300 watt panels. These paired 12 volt panels CAN be run in parallel with the big panels. Don't series wire them with the big panels because the lower current will pull down the whole string, making the 300 watt panels act like 200 watt panels.
You can series wire two 100 watt panels to get similar voltage to the 300 watt panels. These paired 12 volt panels CAN be run in parallel with the big panels. Don't series wire them with the big panels because the lower current will pull down the whole string, making the 300 watt panels act like 200 watt panels.
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