Thought I should share some thoughts about Lithium Iron Phosphate aka LiFeP04 or LFP in this thread. I am not going into other Lithium chemistry like Cobalt, Manganese, or other types because for Solar LFP and Renewable Energy applications IMO LFP is the only chemistry that works economically and technically.
So what are some of the known facts about LFP, and how do we use those facts to get the most out of them:
So how does one best manage LFP to get the most out of it or most bang for the buck? Well first thing to look at is we never want to mess with the ends of the discharge curve. That being completely Discharged or Fully Charged, especially the Completely Discharged portion as that is DEATH for all Lithium batteries. Fully charged LFP offers us some room to play with which I will get to in a minute discussing Battery Management Systems aka BMS.
Lithium batteries unlike Pb operate best in a charge range of 90% SOC and down to 10% SOC. Operating in that range increases cycle life about 50% or 2000 up to 3000 cycles. So how do we do that? Answer is with some form of BMS. Trick is there is no definition of what BMS actually is. It can be something as simple as volt meter to monitor pack voltage, to managing each cell voltage under charge and discharge, and everything in between.
BMS basically falls into two categories of; Top Balance and Bottom Balance. Which is better? IMHO something in-between with bias to Bottom Balance with Low Voltage Disconnect aka LVD.
Today the manufactures of LFP BMS are Top Balance systems, but that has a flaw that comes from Pb mentality of keeping Pb batteries at 100% SOC to maximize cycle life. Pb batteries do not like being discharge and operated in Partial State of Charge aka PSOC. For Pb anything less than 100% SOC is a slow death. All Lithium batteries are best operated in PSOC range less than 100 % and greater that 0%. At 100 % stresses lithium, and at 0% is instant death or a brick. For maximum cycle life 90% or less, and 10% or higher. So as you can see there is already one flaw with Top Balance going to 100% or 4.2 volts per cell.
To go one step further using Top Balance is assuming Best Case that all batteries are created equal when in fact they are NOT. What I mean is when you buy say a 100 AH LFP cell, not every cell is 100 AH. Fortunately after many thousands of test by third parties when you buy a 100 AH cell none lest less than 100 AH, but none test the same. Realistic range is 102 up to 115 AH which is a good thing. Problem is if we use Top Balance we calibrate for Best performance. Imagine we have a car with 4 gas tanks that are supposed to be 10 gallons. But in reality range 9 to 11 gallons and we only monitor the 11 gallon tank level. See a problem with that idea? When we fill up all four tanks are full, but have different capacities. We go driving and monitor the 11 gallon tank, when we see or assume that tank has two gallons left we shut down. Problem is we completely drained the 9 gallon tanks to never be able to hold any more fuel. We turned it into a BRICK. Why because we Referenced to BEST CASE which is a huge No-No in design.
What if we referenced to Worse Case or empty tank of 0% plus a little more so we never flirt with empty. That is BOTTOM BALANCE my friends. How do we do that? Real simple it is done initially by discharging the batteries when we put them into service. How? When we receive the batteries we connect them all in parallel and let them sit for a day. Then we put a load on them and discharge to 2.75 volts. Let them sit for a while and keep discharging a little until they come to rest at between 2.5 to 2.75 volts. We have now referenced the DO NOT CROSS LINE on the bottom or instant DEATH. FWIW 2 volts is the mile high cliff in which you fall to death If you reach it.
So now let’s put that to practice in a BMS. We initially receive our cells from the manufacture and BOTTOM BALANCE. We look for a BMS that monitors all cell voltages. We install a LVD that will disconnect the battery pack when any cell discharges to about 10% SOC or 2.9 volts. We charge at as high of a current until the first cell hits 3.75 volts that means setting your charge controller for 15 volts for every 12 volts to force it into CONSTANT CURRENT. When the first cell reaches 3.75 volts (weakest cell) we go to FLOAT of 3.2 volts per cell or 12.8 volts for every 12 volts of battery. Going to float stops charging the batteries, but leaves the panels available for any load after the batteries are fully charged.
Watch this video and it should explain what I may have missed.
So what are some of the known facts about LFP, and how do we use those facts to get the most out of them:
- Today LFP has the longest Cycle Life of all the battery chemistries from 100% to 20% State of Charge aka SOC. Side note Pb or lead acid has longer life in a narrow range of 100 to 75% SOC of about 30%.
- 100 wh/Kg specific Energy Density or roughly 3 times more than Lead Acid making them lighter and additionally smaller volume which is why they are used in Electric Vehicles aka EV.
- Very low internal resistance aka Ri. This means they can be charged and discharged very fast, very high charge/discharge efficiency and for RE use eliminates Peukert Law Effect.
- Negative coefficient RI meaning their Ri is highest at full charge, and lowest at completely discharged. That means a very flat charge/discharge cure, and will die trying to give everything they have to provide power. When a LFP fails it fails Short Circuit whereas all others fail open circuit. That means you still work at reduced voltage assuming the other batteries in the string have something left to give.
- Of all the Lithium batteries has the highest over charge tolerance of about .7 volts per cell compared to .1 volts of other Lithium chemistry.
- Lowest watt hour capacity cost of lithium chemistry. On the order of $0.30 to $0.45 per wh. For reference a Pb cost $0.09 on the low end for a 1 year battery and $0.24 per Kwh for a 5 year Pb battery.
So how does one best manage LFP to get the most out of it or most bang for the buck? Well first thing to look at is we never want to mess with the ends of the discharge curve. That being completely Discharged or Fully Charged, especially the Completely Discharged portion as that is DEATH for all Lithium batteries. Fully charged LFP offers us some room to play with which I will get to in a minute discussing Battery Management Systems aka BMS.
Lithium batteries unlike Pb operate best in a charge range of 90% SOC and down to 10% SOC. Operating in that range increases cycle life about 50% or 2000 up to 3000 cycles. So how do we do that? Answer is with some form of BMS. Trick is there is no definition of what BMS actually is. It can be something as simple as volt meter to monitor pack voltage, to managing each cell voltage under charge and discharge, and everything in between.
BMS basically falls into two categories of; Top Balance and Bottom Balance. Which is better? IMHO something in-between with bias to Bottom Balance with Low Voltage Disconnect aka LVD.
Today the manufactures of LFP BMS are Top Balance systems, but that has a flaw that comes from Pb mentality of keeping Pb batteries at 100% SOC to maximize cycle life. Pb batteries do not like being discharge and operated in Partial State of Charge aka PSOC. For Pb anything less than 100% SOC is a slow death. All Lithium batteries are best operated in PSOC range less than 100 % and greater that 0%. At 100 % stresses lithium, and at 0% is instant death or a brick. For maximum cycle life 90% or less, and 10% or higher. So as you can see there is already one flaw with Top Balance going to 100% or 4.2 volts per cell.
To go one step further using Top Balance is assuming Best Case that all batteries are created equal when in fact they are NOT. What I mean is when you buy say a 100 AH LFP cell, not every cell is 100 AH. Fortunately after many thousands of test by third parties when you buy a 100 AH cell none lest less than 100 AH, but none test the same. Realistic range is 102 up to 115 AH which is a good thing. Problem is if we use Top Balance we calibrate for Best performance. Imagine we have a car with 4 gas tanks that are supposed to be 10 gallons. But in reality range 9 to 11 gallons and we only monitor the 11 gallon tank level. See a problem with that idea? When we fill up all four tanks are full, but have different capacities. We go driving and monitor the 11 gallon tank, when we see or assume that tank has two gallons left we shut down. Problem is we completely drained the 9 gallon tanks to never be able to hold any more fuel. We turned it into a BRICK. Why because we Referenced to BEST CASE which is a huge No-No in design.
What if we referenced to Worse Case or empty tank of 0% plus a little more so we never flirt with empty. That is BOTTOM BALANCE my friends. How do we do that? Real simple it is done initially by discharging the batteries when we put them into service. How? When we receive the batteries we connect them all in parallel and let them sit for a day. Then we put a load on them and discharge to 2.75 volts. Let them sit for a while and keep discharging a little until they come to rest at between 2.5 to 2.75 volts. We have now referenced the DO NOT CROSS LINE on the bottom or instant DEATH. FWIW 2 volts is the mile high cliff in which you fall to death If you reach it.
So now let’s put that to practice in a BMS. We initially receive our cells from the manufacture and BOTTOM BALANCE. We look for a BMS that monitors all cell voltages. We install a LVD that will disconnect the battery pack when any cell discharges to about 10% SOC or 2.9 volts. We charge at as high of a current until the first cell hits 3.75 volts that means setting your charge controller for 15 volts for every 12 volts to force it into CONSTANT CURRENT. When the first cell reaches 3.75 volts (weakest cell) we go to FLOAT of 3.2 volts per cell or 12.8 volts for every 12 volts of battery. Going to float stops charging the batteries, but leaves the panels available for any load after the batteries are fully charged.
Watch this video and it should explain what I may have missed.
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